Graphite Intercalation Compounds and Applications by Toshiaki Enoki

Cover of: Graphite Intercalation Compounds and Applications | Toshiaki Enoki

Published by Oxford University Press, USA .

Written in English

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The Physical Object
Number of Pages456
ID Numbers
Open LibraryOL7388772M
ISBN 100195128273
ISBN 109780195128277

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Graphite Intercalation Compounds and Applications - Kindle edition by Enoki, Toshiaki, Suzuki, Masatsugu, Endo, Morinobu. Download it once and read it on your Kindle device, PC, phones or tablets.

Use features like bookmarks, note taking and highlighting while reading Graphite Intercalation Compounds and : $ This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds.

The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and Cited by: For many decades, graphite intercalation compounds (GICs) have been investigated from the viewpoints of physics, chemistry, materials science, and engineering (or technological) applications.

1–4 Among various kinds of GICs, special attention has been paid to the first-stage metal compounds, partly because superconductivity is observed mostly. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and.

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ISBN: OCLC Number: Description: xi, pages: illustrations ; 25 cm: Contents: 1: Introduction2: Synthesis and Intercalation Chemistry3: Structures and Phase Transitions4: Lattice Dynamics5: Electronic Structures6: Electron Transport Properties7: Magnetic Properties8: Surface Properties and Gas Adsorption9: GICs and Batteries Highly Conductive.

Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems.

They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity.

This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds.

The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and. Alkali Metal Graphene Plane Graphite Intercalation Compound Graphite Lattice Pristine Graphite These keywords were added by machine and not by the authors.

This process is experimental and the keywords may be updated as the learning algorithm by: 5. The second volume will also contain a chapter on applications of graphite intercalation compounds.

There have been a number of reviews written on selected aspects of these compounds in various journals and conference proceedings during the last couple of years, but this is the first comprehensive review since the thorough overview provided by M.

The properties of graphite intercalation compounds (GIC's) are discussed with respect to possible applications. Five families of intercalates give high electrical conductivity to GIC's: pentafluorides leading to high conductivity, 10 Graphite Intercalation Compounds and Applications book S/m (higher than metallic copper); metal chlorides; fluorine and alkali metals with bismuth giving relatively high conductivity of the order of 10 7 S/m plus Cited by:   The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and Book Edition: 1.

Expanded graphite (EG) is a type of worm-like carbon material prepared by the thermal expansion of graphite intercalation compounds (GICs), and is formed by the insertion of atomic or molecular.

Materials with layered structures remain an extensively investigated subject in current physics and chemistry.

Most of the promising technological applications however deal with intercalation compounds of layered materials. Graphite intercalation compounds have now been known for a long time. Graphite intercalation compounds are a type of graphite compounds.

They are interstitial compounds in which the foreign species (the intercalate) is included in the interplanar sites of the. @article{osti_, title = {Formation of lithium-graphite intercalation compounds in nonaqueous electrolytes and their application as a negative electrode for a lithium ion (shuttlecock) cell}, author = {Ohzuku, Tsutomu and Iwakoshi, Yasunobu and Sawai, Keijiro}, abstractNote = {Electrochemical reduction of natural graphite was carried out in 1M LiClO[sub 4] ethylene carbonate (EC)/1,2.

Graphite Intercalation Compounds I by Hartmut Zabel,available at Book Depository with free delivery : Hartmut Zabel.

Graphite forms intercalation compounds with some metals and small molecules. In these compounds, the host molecule or atom gets "sandwiched" between the graphite layers, resulting in a type of compound with variable stoichiometry.

A prominent example of an intercalation compound is potassium graphite, denoted by the formula KC ry: Native mineral. The insertion of guest species in graphite is the key feature utilized in applications ranging from energy storage and liquid purification to the synthesis of graphene.

Recently, it was discovered that solvated-Na-ion intercalation can occur in graphite even though the insertion of Na ions alone is thermodynCited by: applications that requires a high conductivity and wear resistance.

The stages of Graphite Intercalation Compounds are labeled as Stage 1, Stage 2, etc. and it is used to identify the layers of graphite between a layer of : Kyle Kalbus. CiteSeerX - Document Details (Isaac Councill, Lee Giles, Pradeep Teregowda): A broad review of recent research work on the preparation and the remarkable properties of intercalation compounds of graphite, covering a wide range of topics from the basic chemistry, physics and materials science to engineering applications.

Contents page. Most of the promising technological applications however deal with intercalation compounds of layered materials. Graphite intercalation compounds have now been known for a long time.

Intercalation in transition metal dichalcogenides, on the other hand, has been investigated only recently. Graphite Intercalation Compounds and Applications. Oxford University Press. ISBN Most Cited Papers. Suzuki has published over scientific papers.

The following is a short list of some of his most cited papers. Suzuki M, Masatsugu (). "Magnetic-Properties of Stage 2 CoCl2-Graphite Intercalation Compound".Alma mater: Yokohama National University.

The research on graphite intercalation compounds often acts as a forerunner for research in other sciences. For instance, the concept of staging, which is fundamental to graphite intercalation compounds, is also relevant to surface science in connection with adsorbates on metal surfaces and to high-temperature superconducting oxide layer : Hartmut Zabel.

Graphite-intercalated compounds (GICs): GICs result from the insertion of atomic or molecular layers of different chemical species called intercalant between graphene sheets of the host graphite material [5, 12, 13, 14].

GIC can be categorized into two depending on the character of their bonding, that is, covalent GICs and ionic by: 2. We report synthesis and transport properties of the minimal graphite intercalation compound, a ferric chloride (FeCl3)n island monolayer inside bilayer graphene.

Chemical doping by the intercalant is simultaneously probed by micro-Raman spectroscopy and Hall measurements.

Quantum oscillations of conductivity originate from microscopic domains of intercalated and unintercalated by: The diverse properties of graphite intercalation compounds suggest a number of applications of these materials to mechanical, electrical and chemical engineering processes.

Though graphite intercalation compounds are not yet widely used in industrial applications, the parent compound graphite is an extensively used industrial material.

Yazami is a graduate of the Grenoble Institute of Technology, (INPG) where he also received a Ph. degree in Battery research. Rachid Yazami in the battery lab at Caltech.

Yazami's research project included a study of graphite intercalation compounds for lithium battery applications. In he joined the French National Centre for Known for: graphite anode in lithium ion. Graphite intercalation compounds (GICs) are complex materials having a formula CX m where the ion X n+ or X n− is inserted (intercalated) between the oppositely charged carbon layers.

Typically m is much less than 1. These materials are deeply colored solids that exhibit a range of electrical and redox properties of potential applications.

Graphite intercalation compounds (GIC) possess a broad range of unique properties that are not specific to the parent materials. While the stage transition, changing the number of graphene layers sandwiched between the two layers of intercalant, is fundamentally important and has been theoretically addressed, experimental studies revealed only macroscopic parameters.

Advanced materials for high temperature applications. New ways of elaboration; Impedances of electrochemical systems: Terminology, nomenclature and representation - Part I: Cells with metal electrodes and liquid solutions (IUPAC Recommendations ) Nomenclature and terminology of graphite intercalation compounds (IUPAC Recommendations )Cited by: In particular, unlike pure graphite, some graphite intercalation compounds are found to superconduct.

The first of these to be reported 1,2 was C8K, which has a superconducting transition temperature of K. Interestingly, while the metastable high pressure phase C2Li exhibits a superconducting transition at K 6, the compounds C. To explore this behavior we submitted a “model” system, highly-oriented pyrolytic graphite (HOPG)/sulfuric acid (H 2 SO 4), to axial compressive loads from 0 to 8 MPa, and measured the intercalation response in terms of voltage and displacement.

We observed strains greater than 30% between 2 and 6 MPa, confirming the potential of GIC Cited by: 4. "This outstanding reference presents the latest scientific findings concerning the synthesis, structure, thermodynamics, and physical and chemical properties of fluorine- and fluoride-carbon compounds elucidating their practical applications in lithium batteries, superhydrophobic composites, and the electrolytic production of elemental fluorine.".

New Fluorinated Carbons: Fundamentals and Applications is the second volume in Alain Tressaud’s Progress in Fluorine Science series. This volume provides an overview of cutting-edge research and emerging applications using new fluorinated carbon materials such as fullerenes, carbon nanotubes, polycyclic aromatic molecules, carbon nanofibers, and graphenes.

Potassium Intercalated Graphite Introduction Graphite intercalation compounds (GICs) are a unique class of lamellar materials formed by the insertion of atomic or molecular guests between the layer planes of the host graphite.

Electrical, thermal and magnetic properties can be File Size: KB. Intercalation Compounds of Graphite. Annual Review of Materials Science Vol. (Volume publication date August ) Annual Review of Materials Research Chemical Properties of Bone Mineral Integrated multiscale approach for the development of additively manufactured alloys for structural by: Book Description "This outstanding reference presents the latest scientific findings concerning the synthesis, structure, thermodynamics, and physical and chemical properties of fluorine- and fluoride-carbon compounds elucidating their practical applications in lithium batteries, superhydrophobic composites, and the electrolytic production of.

This book encompasses all the disciplines linked in the progress from fundamentals to applications, from description and modelling of different materials to technological use, from general diagnostics to methods related to technological control and operation of intercalation compounds.

The mineral graphite is an allotrope of carbon. Unlike diamond (another carbon allotrope), graphite is an electrical conductor, a semimetal. It is, consequently, useful in such applications as arc lamp electrodes. Graphite is the most stable form of carbon under standard conditions.

The present book is an ideal continuation of this series, as it contains most of the invited and contributed papers of the Trieste International Con ference on the Physics of Intercalation Compounds, held in Trieste, Italy during the week July Ferric Chloride Graphite Intercalation Compounds Prepared From Graphite Fluoride The graphite intercalated compounds (GIC) deintercalated slowly in air at room temperature, but deintercalated quickly and completely at DC.

intercalation with graphite that has not been pretreated with fluorine.

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